Though it's the first time that Google Adwords launched Free voucher codes in India, the company has regularly been offering free vouchers in in other countries (see links below)
A new advertiser can activate their AdWords account with just US$5.00 (INR 225), and can then choose a maximum cost-per-click (CPC) from US$0.01 - US$100.
Rs 1000 Google Adwords Voucher
50 Euro Adwords Vouchers: Sweden, Italy, France, France, Netherlands
Google Adwords Japan - 4000 Yen Voucher